The Hollywood star braved the chilly conditions in a playful floral frock and peep-toe heels.
She swapped her prim up do, which she sported on a visit to Spain on Tuesday, for a tumbling curls for the occasions.
She was joined by co-stars Eva Mendes and Samuel L. Jackson at an abandoned warehouse.
Her new husband Ryan Reynolds was not able to join her because he is currently filming his new movie Paper Man in New York.
The couple married in a low-key ceremony in Canada in September after dating for 18 months.
Rather than a Leicester Square première, the American stars arrived for the screening at the Old Post Office, ahead of the film's world première in New York next week.
Johansson and Mendes both play sexy female characters. Mendes, wearing a ruffled yellow Bill Blass dress and Louis Vuitton heels, said she enjoyed baring her flesh for the film.
'It's so fun because it's not me. The minute I think it's me I wig out but it's so not me. I'm playing a character so if I drop my towel and show my bum it's not my bum.'
Jackson, who plays The Octopus, said his character was the villain to The Spirit's eponymous superhero.
The film also has several fight scenes, but the main character, played by Gabriel Macht, never uses a knife or gun.
Ladies' night: Eva Mendes joined Scarlett at the screening, held at London's Old Post Office
Director and writer Frank Miller said this was to stay faithful to Will Eisner's original comics.
'I do believe I've done the first scenes where the superhero takes people out with snowballs.'
The film is released in the UK on New Year's Day.
High spirits: Scarlett's co-star Samuel L Jackson and director Frank Miller also attended the film's screening
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